Water and Oil repellent / Adhesion control agent MODIPER® F series
MODIPER® FS series
MODIPER® FP series

MODIPER® F series, FS series and FP series are innovative type block copolymers, which is exclusively manufactured with NOF’s developed block polymer technology.
These 3 grades consist of `Functional segment' and `Anchor segment' as right figure, and they can give some unique properties such as `Water and Oil repellent' , `Adhesion control' and more as additives to coating or adhesive materials depending on kinds of Functional segment part.

Structure of MODIPER® F series, FS series and FP series

Introduction of MODIPER® F series, FS series and FP series

MODIPER® F series, FS series and FP series can improve surface properties of water repellency, anti-pollution property, anti-frictional property, tack strength control property and anti-cohesion property of acrylic coating materials or resins with 1-3% additive ratio.
MODIPER® F series, FS series and FP series can be dissolved into various organic solvents and dispersable into acrylic polymers or synthetic resins.
MODIPER® F series, FS series and FP series can make PTFE powder mix well into acrylic coating materials or resins
MODIPER® F series, FS series and FP series do not contain PFOA (Perfluorooctanoic acid) material.
MODIPER® F series, FS series and FP series do not affect the stability and thermal properties of base coating.
MODIPER® FP series is the suitable additive for electric materials, because MODIPER® FP series doesn't have the silicone component which makes failure in contacting on electric parts.

Properties of MODIPER® F series, FS series and FP series

Lineup of MODIPER® F series, FS series and FP series

Product name	Functional segment	Anchor segment	Solid content (wt.％)	Solvent	Appearance	Property
MODIPER® F206	Fluorinated copolymer	Acrylic copolymer	30	MEK/MIBK	Blue-white transparent liquid	Adhesion control
MODIPER® F606			100	-	White powder	Powder type of F206
MODIPER® F246			30	MEK/MIBM	Blue-white transparent liquid	Anti-Pollution
MODIPER® F3636			30	Paraffin solvent	Transparent liquid	Highly Water Repellency
MODIPER® F226			20	IPA/Water	Blue-white transparent liquid	Environmentally friendly
MODIPER® FS710-1	Silicone copolymer	Acrylic copolymer	15	MEK/Toluene	Transparent liquid	Normal grade
MODIPER® FS700			100	-	White powder	Powder type of FS710-1
MODIPER® FS720			15	MEK	Transparent liquid	Highly Water Repellency
MODIPER® FS730			30	MEK	Transparent liquid	Anti-mar
MODIPER® FS770			15	IPA/Water	White liquid	Environmentally friendly
MODIPER® FP100	Non-Silicone copolymer	Acrylic copolymer	30	Toluene/DMF	Blue-white transparent liquid	Adhesion control

MEK: ：Methyl Ethyl Ketone
MIBK: ：Methyl Iso-butyl Ketone
IPA: ：Isopropyl alcohol
DMF: ：Dimethylformamide

Appearance of MODIPER® F series, FS series and FP series

Basic properties of MODIPER® F series

Test item			Test method	Unit	F206	F606	F246	F3636	F226
Viscosity			JIS K 7117 (1987)	P	0.3	-	0.3	0.1	0.7
Hydroxyl value			JIS K 0070 (1992)	mgKOH/g	55	55	2	0	30
Static contact angle 1)	Water		JIS R 3257 (1999)	Angle（°）	110	110	110	110	115
Static contact angle 1)	n-Hexadecane			Angle（°）	75	75	75	50	95
Dynamic contact angle1)	Water	Advance contact angle		Angle（°）	120	120	120	125	110
	Water	Receding contact angle		Angle（°）	65	65	65	90	20
	n-Hexadecane	Advance contact angle		Angle（°）	70	70	70	80	80
	n-Hexadecane	Receding contact angle		Angle（°）	33	33	33	20	15
Thermal properties	TGA2)	1％ weight loss temperature	JIS K 7120 (1987)	℃	170	170	170	235	165
Thermal properties	TGA2)	5％ weight loss temperature	JIS K 7120 (1987)	℃	250	250	250	300	260

1) test plaque：glass、solid content：10wt.%、dry condition：23℃×24h
2) Thermo Gravimetric Analysis(Rate of temperature rise: 10℃/min in a nitrogen atmosphere)

Dynamic contact angle

Dynamic contact angle consists of 2 type contact angle, Advancing contact angle (θa) and Receding contact angle (θr). In case the Receding contact angle (θr) shows low level as shown in Fig. A, the test liquid doesn't have good water and oil repellent level. On the other hand, in case the Receding contact angle (θr) shows low level as shown in Fig. B, the test liquid has excellent water and oil repellent level.

Basic properties of MODIPER® FS series

Test item			Test method	Unit	FS710-1	FS700	FS720	FS730	FS770
Viscosity			JIS K 7117 (1987)	P	0.1	-	0.1	0.1	0.5
Hydroxyl value			JIS K 0070 (1992)	mgKOH/g	60	60	0	0	195
Static contact angle1)	Water		JIS R 3257 (1999)	Angle（°）	105	105	105	95	75
Static contact angle1)	n-Hexadecane		JIS R 3257 (1999)	Angle（°）	20	10	20	25	25
Thermal properties	TGA2)	1％ weight loss temperature	JIS K 7120 (1987)	℃	170	170	200	170	120
Thermal properties	TGA2)	5％ weight loss temperature	JIS K 7120 (1987)	℃	190	190	240	210	230

1) test plaque：glass、solid content：FS700→20wt.%、FS710-1, FS720, FS730→30wt.%、FS770→10wt.%、dry condition：23℃×24h
2) TGA：Thermo Gravimetric Analysis(Rate of temperature rise: 10℃/min in a nitrogen atmosphere)

Basic properties of MODIPER® FP series

Product	Appearance	Solvent [wt%]	Solid content [wt%]	Viscosity [P]	Hydroxyl value [mgKOH/g]
MODIPER® FP100	Light yellow transparent liquid	Toluene/DMF=60/40	30	0.4	27

Solubility of MODIPER® F series and FS series

Solvent	F206 F606	F246	F3636	F226	FS710-1	FS700	FS720	FS730	FS770
Acetone	✔	✔	×	✔	✔	✔	✔	✔	✔-
Methyl Ethyl Ketone	✔	✔	×	✔	✔	✔	✔	✔	×
Methyl Iso-butyl Ketone	✔	✔	✔	✔	✔	✔	✔	✔	×
Ethyl Acetate	✔	✔	×	✔	✔	✔	✔	✔	×
Butyl Acetate	✔	✔	✔	✔	✔	✔	✔	✔	×
Tetrahydrofuran	✔	✔	✔	✔	✔	✔	✔	✔	✔-
Methanol	×	×	×	×	×	×	×	×	✔-
Ethanol	✔-	✔-	×	✔-	✔	✔-	✔-	×	✔
n-Butanol	×	✔	×	✔-	✔	×	✔	✔-	×
Ethylene Glycol Monomethyl Ether	✔	✔	×	✔	✔	✔	✔	✔	✔
Ethylene Glycol Monoethyl Ether	✔	✔	×	✔	✔	✔	✔	✔	✔
n-Hexane	×	×	✔	×	✔-	×	✔-	✔-	×
Toluene	×	✔-	✔	✔-	✔	✔	✔	✔	×
Xylene	×	✔-	✔	✔-	✔	×	✔	✔	×
Dimethylformamide	✔	✔	×	✔	✔	✔	✔	✔	✔
Chloroform	✔	✔	✔	✔-	✔	✔	✔	✔	×

Solubility was evaluated by diluting to 1wt.% active ingredient into each solvent

✔：Soluble ✔-：Partly soluble ×：Insoluble

Water and Oil repellent / Adhesion control agent MODIPER® F seriesMODIPER® FS seriesMODIPER® FP series