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Anti-pollution

Improving anti-pollution property of Unsaturated Polyester resins with MODIPER® F246

Water and Oil repellent of Unsaturated Polyester resins can be improved with adding MODIPER® F246.
Consequently, water stains and oil stains can be removed easily.

Preparation of test plaque

■ Composition

material Compound Formulas (part by weight)
Resin Unsaturated polyester resin 70
Low Profile additive Polystyrene 1) 30
Inorganic filler Calcium Carbonate 160
Release agent Zinc Stearate 4
Thickener Magnesium Oxide 2
Curing agent PERHEXYL A 2) 1.4
Retarder Benzoquinone 3) 1
Anti-pollution agent 4) MODIPER® F246 2
Reinforcing material Glass fiber 28
  1. 1) 30wt.% styrene solution
  2. 2) t-hexyl peroxyacetate of NOF CORPORATION
  3. 3) 5wt.% diethylene glycol solution
  4. 4) weight of active element

■ Aging condition

  • ・Condition : 40℃×24h

■ Molding condition

  • ・Equipment : Compression molding machine
  • ・Mold temperature : Upper/Lower=140℃/130℃
  • ・Pressure : 10MPa
  • ・Curing time : 5min

Test method and criteria

Anti-pollution property was evaluated from residual rate of water scale after wiping off the scale which was simply created with aqueous solution containing pigment.

  • ・Testing standard : static contact angle measurement (JIS R 3257 (1999))
  • ・Test device : contact angle meter Drop Master 500 (Kyowa interface science Co., Ltd.)
  • ・Procedure : measure the contact angle 30sec after dropping water or solvent on surface.
  • ・Test solvent : Water, Oleic acid
Test method

Test result

Static contact angle was improved with adding MODIPER® F246, and Anti-pollution property was also improved consequently.

before wiping off
before wiping off
After wiping off, non-additive
After wiping off, non-additive
After wiping off, containing MODIPER® F246
After wiping off, containing MODIPER® F246
Fig. Anti-pollution effect of MODIPER® F246
Fig. Anti-pollution effect of MODIPER® F246